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You did say you've sprayed acrylics over enamels with no problem, but were they water-based acrylics?. Krylon's "acrylic lacquer" is definitely not water based.
There’s probably a prototype for that, and you just discovered a technique!
I suspect it has a lot to do with the enamel formulation. In my failure case, it was enamel mixed at a Miller Paint store because I wanted a custom Loewy green to repaint an NP passenger car. I don't think that is the same formula as, say, the Testors enamels in the little glass bottles. When I showed the guys in the store what happened they knew instantly - "No! Don't use lacquers over enamel", they told me. And they suggested something with a urethane base instead.
Don’t use Rustoleum on anything other than metal. If it don’t rust, don’t paint it with that stuff.
CRL: I tend to agree.DaveFoxx: For roads, even styrene roads, an aggressive paint may not be a bad thing. I used a can of "cold galvanizing compound" for most of my paved roads. It did craze the surface of the styrene sheet a little, but the cracks looked quite natural after weathering, and it definitely won't scrape off. It wasn't shiny at all, a nice flat medium gray. I bought a second can, and it was a shiny silver color, and the color rubs off the surface very easily, although the base stays stuck to the plastic. Got lucky on the first can - apparently it was defective!