A too-tight curve will cause the cars to "corner" even if the coupler is working fine. About the only way to fix that is to move the cars farther apart.
In this case, that might be easy. As far as I know, Rapido couplers are standard MT 1015s. Take the box apart and install 1016s, with the longer shank, and it should work. Keep the 1015s, and when you have wider curves, put them back in.