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I use a little of the stuff from the bottom of my grill in much the same way as @randgust
I am a little confused about what "ash" from a steam locomotive looks like. How is it different from the grimy black "cinders" that we see in rail yards, sub-roadbed fill, etc.? I would think that the really fine, "fluffy" stuff would get sucked up the locomotive stack by the forced draft over the firebox, and it would be the cinders that are left behind to get dumped into the ash pit. But, I was so young when that was actually happening that my Mom wouldn't let me go play in an ash pit, so I really don't know.
I would think ashes would go flying out of a gondola as it was pulled along in a consist. Perhaps "ash pit" was just a name for the clinkers dump. Why RRs not call it a cinder dump, who knows?