Here is a collection of aerosol-can nozzles I collected over the years for decanting. This photo actually made into one of the TRW banners. I'm proud of that!

Whenever I see nozzles which naturally come with a tube (like WD40 for example), I save them. I also sometimes open up empty cans and extract the siphon tube inside. Some of the nozzles are modified to accept those tubes. I have large variety because there are multiple types of valves on cans. This way I have a good chance to have a nozzle with a tube that fits the stem.

Once I'm done decanting, I immediately put the pipette on the nozzle's stem and place the tube in glass with some lacquer thinner. I then pump the pipette to flush the still-fresh paint out of the nozzle. This makes the cleanup very easy. If I waited too long, ,some of the partially hardened paint would not flush out easily.
As far as degassing goes, that is a really good idea! The propellant inside the can (usually propane) is partially dissolved in the paint (like carbonated drink). When the paint is decanted, some of the propellant remains in the paint. That is especially true since decanting process cools the paint as it comes out of the nozzle. Cool liquid retains more propellant. If the decanted paint is in a glass jar, when you swirl the paint in the jar you can see the paint bubbling.
Like Bryan, I just screw on the cap on the bottle, but don't tighten it. A day or so in room temperature will let most of the gas come out of the paint. If you don't do that, then later shook the jar and open it, the paint will come out spraying all over you (again, like shaking a soft drink can then opening it). When I need the decanted paint in a hurry, I place the decanted paint containers (with loosely fit cap) in my dehydrator to warm up the paint. Then I can use it in couple hours.
Autommotive modelers often decant paint. For some more unconventional ways to decant see:
http://www.modelcarsmag.com/forums/topic/151903-decanting-spray-paint/http://www.modelcarsmag.com/forums/topic/132876-decanting-spray-paint/