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I'm convinced by the chatter that this is the one to buy for the best out-of-the-box experience for an FDM noob. On top of that, the thermal enclosure is something I felt from experience with plastics in general would yield better results from filament deposition.
Materials? Got me. Gut has me leaning toward ABS, but that's primarily from fooling with ABS fabrication for six decades, and knowing which glues and solvents work (and which don't!). Also have a little experience with PLA output and that when the build delaminates, there's no glue beyond CA that'll fix it, and then not well.