There's a casting group at Yahoo Groups - it's pretty inactive but specific questions usually bring some reasonable responses. Most of those guys are really into casting, so the advice will be centered on getting vac chambers and the like - - good ideas all, but no really necessary for the kind of parts you're making. (You can afford to cast 10 pieces to get one truly "good" part.
Craig Bisgeier has a number of items about the experience he has had casting parts, structures, and complete freight cars for his Housatonic RR on his web site -
http://www.housatonicrr.com/One of the best sources for getting started I know of is Tom Piccirillo's "Making More Than One" in the May, 2002 issue of that god awful magazine, Model Railroader.

Some basic advice - watch for undercuts since those are the kind of voids where air bubbles will get trapped - think about how the resin will flow before you make the master or the mold, and pay particular emphasis on minimizing air bubbles.
Good luck!
Hope this helps,
Marty